Formation of polyelectrolyte-micelle complexes
نویسندگان
چکیده
منابع مشابه
Cryo-TEM of Polyelectrolyte-Micelle Complexes
Cryo-TEM was carried out on samples containing polyelectrolyte-micelle complexes, formed by combining poly(diallyldimethylammonium chloride) (PDADMAC), a strong cationic polyelectrolye, with oppositely charged mixed micelles of sodium dodecyl sulfate (SDS) and nonionic Triton X-100 (TX100), in 0.40 M NaCl. Complexation appears to involve the formation of micelle-rich regions, presumably within ...
متن کاملCluster formation in polyelectrolyte-micelle complex coacervation.
The temperature-induced liquid-liquid phase transition (complex coacervation) of a polycation-anionic/nonionic mixed micelle system was examined over a range of macroion concentrations and polycation molecular weights (MW) using turbidimetry and dynamic light scattering (DLS). DLS revealed a progressive increase in complex/aggregate size with temperature up to the phase transition at T(φ), foll...
متن کاملEffects of Salt on Polyelectrolyte-Micelle Coacervation
Turbidity, dynamic light scattering, and electrophoretic mobility were used to study the effects of added salt on coacervation in the system composed of the strong cationic polymer poly(diallyldimethylammonium chloride) (PDADMAC) and oppositely charged mixed micelles of Triton X-100 (TX100) and sodium dodecyl sulfate (SDS). The phase behavior in the range of ionic strengths from 0.05 to 0.60 M ...
متن کاملMesophase separation in polyelectrolyte-mixed micelle coacervates.
Mesophase separation has been identified in a polycation/anionic-nonionic mixed micelle system formed by the coacervation of poly(diallyldimethylammoniumchloride)/sodium dodecylsulfate-Triton X-100 in 0.40 M NaCl. The resultant dense, optically clear fluid was studied by turbidity, dynamic light scattering (DLS), and rheology. The presence of two diffusion modes in DLS points to microscopic het...
متن کاملPolyelectrolyte-Modified Microemulsions: Formation of Nanoparticles in the Presence of Anionic and Cationic Polyelectrolyte
The paper is focused on the formation of calcium phosphate nanoparticles (CP) in polyelectrolyte-modified microemulsions, in a microemulsion template phase consisting of cyclohexane, water, anionic surfactantant and cosurfactant, in the presence of anionic and cationic polyelectrolyte. It is shown that polyelectrolyte, can be incorporated into the individual inverse microemulsion droplets. The ...
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ژورنال
عنوان ژورنال: Langmuir
سال: 1991
ISSN: 0743-7463,1520-5827
DOI: 10.1021/la00058a001